A 32-year-old driver from the Devizes area has died in a crash on the A345 near Pewsey.
The incident took place shortly after 6.30pm on Sunday when a silver Renault Clio and a black Chrysler pick-up were in collision on Swan Road, near Manningford Abbots.
The driver of the Chrysler suffered fatal injuries.
Police are appealing for witnesses to the incident and anyone who saw either vehicle at around that time is asked to contact the serious collision investigation team through the 101 non-emergency number.
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